Nitrogen trifluoride or NF3 is a nitrogen halide compound that is slightly water-soluble. That noticeable qualities include gift colorless and carrying a musty or moldy odor.

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NF3 has actually a molar massive of around 71.002 g/mol and also a density of 3.003 kg/m3.

One the the main reasons why this chemical compound is critical topic is due to the fact that it is a greenhouse gas. That is claimed to have actually quite high worldwide warming potential yet a comparatively low value of radiative forcing.

Other than being a greenhouse gas and also contributing come the climatic adjust of the planet, NF3 has actually several applications. The is used to develop chemical fluoride lasers and remove silicon-based compounds during semiconductor manufacturing. Also, nitrogen trifluoride is a ingredient of high-energy fuels.

NF3 is a toxicity non-flammable gas that deserve to prove to be harmful if inhaled. It deserve to lead to a problem called methemoglobinemia.

NF3 Lewis Structure

Nitrogen trifluoride is a chemistry molecule having actually one atom that nitrogen and three atom of fluorine.

In Lewis Structure, we shot to discover a suitable pictorial depiction of a molecule to have actually an idea that the chemical bonding occurring inside the molecule structure.

Before we proceed, we need to learn around a really important concept: Valence Electrons.

The electrons the are current in the outermost shell of an atom nucleus are recognized as valence electrons. The combine or the binding power or volume is termed as Valency.


As we have the right to see, the over diagram provides us the regular table. Nitrogen belong to team 15 and fluorine, being a halogen, belong to team 17.

nitrogen has 5 and also fluorine has seven valence electrons.

The total variety of valence electron in a NF3 molecule = 5 + 7*3 = 26.

Nitrogen is much more electropositive 보다 fluorine and also we will keep it in the center. This is since electronegative atoms room usually wake up to share electrons. Electropositive atoms, ~ above the other hand, are much more prone come share and assist in bond formation.


In Lewis Structure, we denote valence electron by dot notations. Permit us map out a probable Lewis structure for Nitrogen Trifluoride.


We have actually put the valence dot structures and also made a sketch of the NF3 molecule.

Let us now recognize the next important ide of Lewis Structure:

Octet Rule

The main team (group 1- 17) facets tend to acquire the electronic configuration of the outermost covering of noble gas elements.

Noble gases choose Neon, Argon, Xenon have eight electrons in their valence shells. Main group aspects present in the same duration have this tendency to accomplish a valency of eight while developing bonds inside a molecule.

This is known as the octet rule.

Let us inspect if we have actually fulfilled the octet dominance in our Lewis structure.

The above graphical representation of NF3 mirrors that all the three bordering Fluorine atoms and also the central Nitrogen atom have completed octet fulfillment.

Our last step towards obtaining the required structural lay out is the principle of official Charge.

The officially charge deserve to be characterized as the electrical charge assigned to any given molecule atom assuming that electrons are constantly shared equally amongst the ingredient elements.

We calculate formal fee via the below-mentioned formula:


Formal fee for Nitrogen atom = 5 – 0.5*6 – 2 = 0.

Formal charge for every Fluorine atom = 7 – 0.5*2 – 6 = 0.

As we deserve to see, all the atoms within the NF3 molecule have the least feasible formal charge values.

Therefore, we have attained our many perfect Lewis structure diagram.

If we indicate solitary bonds by straight lines, a 2D depiction of the Nitrogen Trifluoride molecule will certainly look like this:


NF3 molecular Geometry


Molecular geometry or molecular form is crucial concept the we must decipher while we are learning the chemical bonding of any type of chemical composition.

While Lewis Structure gives us an idea around the inner bond types and valence electron sharing inside a given molecule, it deserve to only define a two-dimensional geometry. To understand the 3D molecular form of the molecule, we have an interesting theory: VSEPR theory.

VSEPR or Valence shell Electron Pair Repulsion version is our go-to theory to guess the molecule geometry of NF3.

Electrons present about the nuclei the constituent atoms of various molecules an outcome in a negatively fee atmosphere. Because these subatomic particles happen to carry an adverse charges, they also develop a repulsive tendency that demands to be decreased to account for molecular stability.

VSEPR theory talks about the minimization the repulsive forces developed by valence covering electrons and helps us predict the perfect molecular geometry.

For the NF3 molecule, us will try to find out the 3D shape.

While we room doing this, remember us will just take right into account the valence electrons roughly the central nitrogen in the polyatomic halide molecule.

AXnEx is the notation that the VSEPR model.

A: the central atom, here Nitrogen will be A.

X stands for the surrounding atoms because that nitrogen, ∴ n = 3.

E stands for lone bag of the central atom, ∴ n = 1.

The result notation will certainly be AX3N1.

Let united state look in ~ the VSEPR notation chart.


According to the VSEPR chart, the molecule geometry of nitrogen trifluoride is trigonal bipyramidal. We can also predict electron geometry via electron groups through VSEPR theory.

In NF3, the central nitrogen atom has four electron teams surrounding it: three single bonds( 3 bonded pairs) and one lone pair.

Therefore, the electron geometry is tetrahedral and the bond angle is about 102.50 degrees.

Note: The bond edge in NF3 is less than that in NH3 fan to the higher electronegativity worth of fluorine.

NF3 Hybridization

Hybridization, a concept of chemistry bonding, is regarded orbitals.

While orbits room fixed routes of electrons approximately the atom nuclei, orbitals are given by the mathematical probability the the presence of electrons in any region of space.

When atomic orbitals come with each other to fuse and type hybrid orbitals, we contact it the orbit hybridization in chemistry.

We have actually several types of atom orbitals prefer s, p, d, f which have various shapes.

We likewise have the presence of numerous hybrid orbitals in a molecule favor sp, sp2, sp3, sp3d, etc.

Note, follow to Valence bond Theory, just atomic orbitals the the very same atom within the molecule can incorporate to form hybridized orbitals in hybridization.

Let us look at the digital configuration that the main Nitrogen atom the the NF3 molecule:

N: 1s2 2s2 2p3

The one 2s orbital and also 2px, 2py, and also 2pz orbitals of ns orbital fuse to kind four hybrid orbitals.

Also, by the ide of steric number,

Steric number = number of atoms external inspection to central atom inside a molecule + variety of lone pair of electron attached to the main atom

The steric number = 3 + 1 = 4.

The hybridization H worth is 4 and the type, therefore, is sp3.


NF3 Polarity

Polarity is the ide of expertise charge separation within a molecule. Electronegativity talks around the degree to i beg your pardon an facet can obtain or get electrons. To recognize polarity, we require to decipher the electronegativity ide as well.

The Pauling Electronegativity graph is the very first and foremost step towards understanding the polar nature of a molecule


As we deserve to see below clearly, Nitrogen and also Fluorine have actually a high distinction in electronegativity.

While Nitrogen has actually an electronegativity value of 3.04, that of fluorine is 3.98 making the difference more than 0.4-0.5.

This shows that there will certainly be a separation of electric charges. Nitrogen will possess a partial hopeful charge (δ+) and fluorine will certainly possess a partial an unfavorable charge (δ-).

Each N-F shortcut will therefore have negative and hopeful poles. This leader to the rise of three polar bonds inside the NF3 molecule.

Now, the polarity the the whole molecule is dependence not only on the nature of bonds but additionally on the the opposite of the molecule. In NF3 we execute not have linear geometry.

Due come the asymmetry resulting from the presence of a lone pair on the central nitrogen atom, we acquire polarity.

NF3 is a polar molecule.

You must also go v the detailed article written on the polarity of NF3.

Note: NF3 is quite less polar 보다 NH3 (since the network dipole minute is less).


NF3 Molecular orbital (MO) Diagram

Molecular orbital concept or MOT is a facility and amazing theoretical method towards knowledge the chemical bonding occurring inside a given molecular structure.

In MOT, we perform not only talk about the combination of AOs (atomic orbitals) of the same atom that the exact same energies yet we consider the orbitals the the molecule as a whole.

Here, the valence electrons of every constituent atoms deserve to be shared inside the molecule. They incorporate to type MOs or molecule orbitals and the complete concept is defined graphically via an MO diagram.

In molecular orbit theory, we consider the orbitals comprise the inner shell electrons to it is in non-bonding orbitals.

Other than this, we have bonding and also anti-bonding orbitals. Anti-bonding orbitals are greater in energy, much less stable, and also contain a node perpendicular to the internuclear axis. Bonding orbitals are much more stable in nature.

N: 1s2 2s2 2p3

F: 1s2 2s2 2p5

Here, the 1s2 orbitals that the four atoms space the nonbonding orbitals.

Here, we have actually attached the MO diagram of one more halide molecule BF3 for reference.

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In this article, we have discussed the chemistry bonding nature inside a molecule that Nitrogen Trifluoride. We have defined the Lewis Structure, VSEPR theory, Hybridization, Polarity, and also MOT chart in detail.